%0 Generic
%A Thompson, Rick
%A Chen, Chun-Hsing
%A Pink, Maren
%A Wu, Gang
%A Mindiola, Daniel J.
%D 2014
%T A Nitrido
Salt Reagent of Titanium
%U https://acs.figshare.com/articles/dataset/A_Nitrido_Salt_Reagent_of_Titanium/2283574
%R 10.1021/ja504020t.s003
%2 https://acs.figshare.com/ndownloader/files/3920023
%K parent imido
%K tBunacnac
%K KCH 2Ph forms
%K nitride
%K 2C
%K parent titanium imido
%K Nitrido Salt Reagent
%X Deprotonation of
the parent titanium imido (tBunacnac)TiNH(Ntolyl2) (tBunacnac– = [ArNCtBu]2CH; Ar = 2,6-iPr2C6H3) with KCH2Ph forms a rare example of a molecular
titanium nitride as a dimer, {[K][(tBunacnac)TiN(Ntolyl2)]}2. From the parent imido or nitride salt, the
corresponding aluminylimido–etherate adduct, (tBunacnac)TiN[AlMe2(OEt2)](Ntolyl2), can be isolated and structurally characterized. The parent
imido is also a source for the related borylimido, (tBunacnac)TiNBEt2(Ntolyl2).
%I ACS Publications