%0 Generic %A Thompson, Rick %A Chen, Chun-Hsing %A Pink, Maren %A Wu, Gang %A Mindiola, Daniel J. %D 2014 %T A Nitrido Salt Reagent of Titanium %U https://acs.figshare.com/articles/dataset/A_Nitrido_Salt_Reagent_of_Titanium/2283574 %R 10.1021/ja504020t.s003 %2 https://acs.figshare.com/ndownloader/files/3920023 %K parent imido %K tBunacnac %K KCH 2Ph forms %K nitride %K 2C %K parent titanium imido %K Nitrido Salt Reagent %X Deprotonation of the parent titanium imido (tBunacnac)­TiNH­(Ntolyl2) (tBunacnac = [ArNCtBu]2CH; Ar = 2,6-iPr2C6H3) with KCH2Ph forms a rare example of a molecular titanium nitride as a dimer, {[K]­[(tBunacnac)­TiN­(Ntolyl2)]}2. From the parent imido or nitride salt, the corresponding aluminylimido–etherate adduct, (tBunacnac)­TiN­[AlMe2(OEt2)]­(Ntolyl2), can be isolated and structurally characterized. The parent imido is also a source for the related borylimido, (tBunacnac)­TiNBEt2(Ntolyl2). %I ACS Publications