A Nitrido
Salt Reagent of Titanium
Rick Thompson
Chun-Hsing Chen
Maren Pink
Gang Wu
Daniel J. Mindiola
10.1021/ja504020t.s003
https://acs.figshare.com/articles/dataset/A_Nitrido_Salt_Reagent_of_Titanium/2283574
Deprotonation of
the parent titanium imido (<sup>tBu</sup>nacnac)TiNH(Ntolyl<sub>2</sub>) (<sup>tBu</sup>nacnac<sup>–</sup> = [ArNC<sup>t</sup>Bu]<sub>2</sub>CH; Ar = 2,6-<sup>i</sup>Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>) with KCH<sub>2</sub>Ph forms a rare example of a molecular
titanium nitride as a dimer, {[K][(<sup>tBu</sup>nacnac)TiN(Ntolyl<sub>2</sub>)]}<sub>2</sub>. From the parent imido or nitride salt, the
corresponding aluminylimido–etherate adduct, (<sup>tBu</sup>nacnac)TiN[AlMe<sub>2</sub>(OEt<sub>2</sub>)](Ntolyl<sub>2</sub>), can be isolated and structurally characterized. The parent
imido is also a source for the related borylimido, (<sup>tBu</sup>nacnac)TiNBEt<sub>2</sub>(Ntolyl<sub>2</sub>).
2014-06-11 00:00:00
parent imido
tBunacnac
KCH 2Ph forms
nitride
2C
parent titanium imido
Nitrido Salt Reagent