10.1021/am5017045.s001 Mei Li Mei Li Yao Wang Yao Wang Yunlong Wang Yunlong Wang Fanglin Chen Fanglin Chen Changrong Xia Changrong Xia Bismuth Doped Lanthanum Ferrite Perovskites as Novel Cathodes for Intermediate-Temperature Solid Oxide Fuel Cells American Chemical Society 2014 Bismuth Doped Lanthanum Ferrite Perovskites Dchem Bi doping conductivity novel cathode material content oxide fuel cells Kchem polarization resistance Oxide Fuel CellsBismuth chemical diffusion coefficient perovskite lanthanum strontium ferrite oxide fuel cell cathode material 0.10 Ω cm 2 oxygen vacancy concentration 2014-07-23 00:00:00 Journal contribution https://acs.figshare.com/articles/journal_contribution/Bismuth_Doped_Lanthanum_Ferrite_Perovskites_as_Novel_Cathodes_for_Intermediate_Temperature_Solid_Oxide_Fuel_Cells/2271214 Bismuth is doped to lanthanum strontium ferrite to produce ferrite-based perovskites with a composition of La<sub>0.8‑x</sub>Bi<sub><i>x</i></sub>Sr<sub>0.2</sub>FeO<sub>3‑δ</sub> (0 ≤ <i>x</i> ≤ 0.8) as novel cathode material for intermediate-temperature solid oxide fuel cells. The perovskite properties including oxygen nonstoichiometry coefficient (δ), average valence of Fe, sinterability, thermal expansion coefficient, electrical conductivity (σ), oxygen chemical surface exchange coefficient (<i>K</i><sub>chem</sub>), and chemical diffusion coefficient (<i>D</i><sub>chem</sub>) are explored as a function of bismuth content. While σ decreases with <i>x</i> due to the reduced Fe<sup>4+</sup> content, <i>D</i><sub>chem</sub> and <i>K</i><sub>chem</sub> increase since the oxygen vacancy concentration is increased by Bi doping. Consequently, the electrochemical performance is substantially improved and the interfacial polarization resistance is reduced from 1.0 to 0.10 Ω cm<sup>2</sup> at 700 °C with Bi doping. The perovskite with <i>x</i> = 0.4 is suggested as the most promising composition as solid oxide fuel cell cathode material since it has demonstrated high electrical conductivity and low interfacial polarization resistance.