Tetrasilane-Bridged
Bicyclo[4.1.0]heptasil-1(6)-ene
Akihiro Tsurusaki
Jun Kamiyama
Soichiro Kyushin
10.1021/ja507279z.s001
https://acs.figshare.com/articles/journal_contribution/Tetrasilane_Bridged_Bicyclo_4_1_0_heptasil_1_6_ene/2254354
Tetrasilane-bridged
bicyclo[4.1.0]heptasil-1(6)-ene <b>1</b> was synthesized by
the reduction of 1,1,2,2-tetrachlorocyclohexasilane <b>2</b> in 12% yield as red-orange crystals. The structure and properties
of <b>1</b> were studied by spectroscopy, X-ray crystallography,
and theoretical calculations. The linkage of the cyclotrisilene moiety
with two tetrasilane chains with <i>tert</i>-butyl groups
remarkably affects its structure and <sup>29</sup>Si NMR spectrum.
2014-09-17 00:00:00
cyclotrisilene moiety
calculation
bicyclo
crystallography
29 Si NMR spectrum
tetrasilane chains
linkage
tetrachlorocyclohexasilane
Bicyclo
crystal
spectroscopy