Construction of Erythrinane Skeleton via Pd(0)-Catalyzed Intramolecular Dearomatization of <i>para</i>-Aminophenols XuRen-Qi GuQing WuWen-Ting ZhaoZhuo-An YouShu-Li 2014 A novel Pd(0)-catalyzed intramolecular arylative dearomatization of <i>para</i>-aminophenol derivatives is described. In the presence of 1.25 mol % [Pd­(C<sub>3</sub>H<sub>5</sub>)­Cl]<sub>2</sub> and 3.75 mol % RuPhos, the arylative dearomatization reaction proceeds smoothly for a broad range of substrates, offering an efficient synthetic route to erythrinane derivatives in excellent yields.