%0 Journal Article %A Agou, Tomohiro %A Wasano, Tatsuya %A Sasamori, Takahiro %A Tokitoh, Norihiro %D 2014 %T Syntheses and Structures of Stable 1‑Aminoalumole Derivatives %U https://acs.figshare.com/articles/journal_contribution/Syntheses_and_Structures_of_Stable_1_Aminoalumole_Derivatives/2227858 %R 10.1021/om501055f.s001 %2 https://acs.figshare.com/ndownloader/files/3863797 %K Aminoalumole %K Stable %K Structures %K ligand exchange reactions %K LiN %K Synthese %K isolable %K aminoalumole %K derivative %K lithium %K diaminoalumoluide %K DerivativesReaction %K bromoalumole %K THF %K toluene %K NMR spectroscopy %K alumole %K analysis %K diaminodialumoluide %X Reaction of an isolable 1-bromoalumole with LiN­(SiMe3)2 in toluene afforded a lithium 1,1-diaminodialumoluide, while in THF the corresponding 1-aminoalumole–THF complex was obtained. These amino-substituted alumole derivatives are characterized by X-ray crystallographic analysis and NMR spectroscopy. The lithium 1,1-diaminoalumoluide and the 1-aminoalumole–THF complex were converted to each other by ligand exchange reactions. %I ACS Publications