%0 Journal Article
%A Agou, Tomohiro
%A Wasano, Tatsuya
%A Sasamori, Takahiro
%A Tokitoh, Norihiro
%D 2014
%T Syntheses and Structures of Stable 1‑Aminoalumole Derivatives
%U https://acs.figshare.com/articles/journal_contribution/Syntheses_and_Structures_of_Stable_1_Aminoalumole_Derivatives/2227858
%R 10.1021/om501055f.s001
%2 https://acs.figshare.com/ndownloader/files/3863797
%K Aminoalumole
%K Stable
%K Structures
%K ligand exchange reactions
%K LiN
%K Synthese
%K isolable
%K aminoalumole
%K derivative
%K lithium
%K diaminoalumoluide
%K DerivativesReaction
%K bromoalumole
%K THF
%K toluene
%K NMR spectroscopy
%K alumole
%K analysis
%K diaminodialumoluide
%X Reaction
of an isolable 1-bromoalumole with LiN(SiMe3)2 in toluene afforded a lithium 1,1-diaminodialumoluide, while in
THF the corresponding 1-aminoalumole–THF complex was obtained.
These amino-substituted alumole derivatives are characterized by X-ray
crystallographic analysis and NMR spectroscopy. The lithium 1,1-diaminoalumoluide
and the 1-aminoalumole–THF complex were converted to each other
by ligand exchange reactions.
%I ACS Publications