10.1021/om5009132.s002
Raúl García-Rodríguez
Raúl
García-Rodríguez
Hayley R. Simmonds
Hayley R.
Simmonds
Dominic S. Wright
Dominic S.
Wright
Formation of a Heterometallic Al<sup>III</sup>/Sm<sup>III</sup> Complex Involving a Novel [EtAl(2-py)<sub>2</sub>O]<sup>2–</sup> Ligand (2-py = 2‑Pyridyl)
American Chemical Society
2014
novel multifunctional dianionic ligand
EtAl
formation
Sm
heterobimetallic sandwich compounds
2014-12-22 00:00:00
Dataset
https://acs.figshare.com/articles/dataset/Formation_of_a_Heterometallic_Al_sup_III_sup_Sm_sup_III_sup_Complex_Involving_a_Novel_EtAl_2_py_sub_2_sub_O_sup_2_sup_Ligand_2_py_2_Pyridyl_/2223409
Controlled
O<sub>2</sub> oxidation of the Sm(II) sandwich compound
[{EtAl(2-py)<sub>3</sub>}<sub>2</sub>Sm] (<b>1a</b>) gives
the Sm(III)/Al(III) compound [{EtAl(2-py)<sub>3</sub>}{EtAl(2-py)<sub>2</sub>O}Sm]<sub>2</sub> (<b>2</b>), containing the novel multifunctional
dianionic ligand [EtAl(2-py)<sub>2</sub>O]<sup>2–</sup>. The formation of an O-bridged Al-O-Sm arrangement in the structure
of <b>2</b> is potentially relevant to the catalytic epoxidation
of styrene with dry air using heterobimetallic sandwich compounds
like <b>1a</b>.