%0 Generic %A Kundu, Subrata %A Mohapatra, Balaram %A Mohapatra, Chandrajeet %A Verma, Sandeep %A Chandrasekhar, Vadapalli %D 2015 %T Polymeric, Molecular and Ionic Organotin Complexes Containing Hypoxanthine, Adenine and 2‑Aminopurine. Synthesis and Supramolecular Structures %U https://acs.figshare.com/articles/dataset/Polymeric_Molecular_and_Ionic_Organotin_Complexes_Containing_Hypoxanthine_Adenine_and_2_Aminopurine_Synthesis_and_Supramolecular_Structures/2218534 %R 10.1021/cg501322w.s002 %2 https://acs.figshare.com/ndownloader/files/3854296 %K 1 D coordination polymers %K 2SnCl %K 3H %K acid %K ratio %K interaction %K Supramolecular StructuresThe reaction %K Ionic Organotin Complexes Containing Hypoxanthine %K 4H %K 2H %K L 1H %K Ph 3Sn %X The reaction of L1H [L1H = 3-(N9-hypoxanthyl)­propanoic acid] with Me3SnCl or (n-Bu3Sn)2O afforded the 1D coordination polymers [Me3Sn­(L1)]n (1) and [n-Bu3Sn­(L1)]n (2), respectively. A similar reaction between L2H [3-{N9-(2-amino­purinyl)}­propanoic acid] with (Ph3Sn)2O in a 2:1 ratio afforded a dimer [(L2)­(Ph3Sn)­L2­{Ph3Sn­(H2O)}]·​3CH3OH·​3H2O (3). The reactions of 2-(N9-adeninyl)­acetic acid (L3H) and 3-(N9-adeninyl)­propanoic acid (L4H) with (Ph3Sn)2O in a 2:1 ratio afforded insoluble intractable products, which, upon addition of dilute HCl in methanol, afforded [{Ph2SnCl3­(H2O)}­(HL3Me)2Cl]·​H2O (4) and [(Ph2SnCl4)­(HL4Me)2] (5). Complexes 15 show an extensive supramolecular organization in the solid state as a result of several intermolecular interactions, prominent among which are the interactions between the nucleobases. %I ACS Publications