Asymmetric Dearomatization of 1‑Aminonaphthalene
Derivatives by Gold-Catalyzed Intramolecular Double C–C Bond
Formation
Junko Oka
Ryuichi Okamoto
Keiichi Noguchi
Ken Tanaka
10.1021/ol503698s.s001
https://acs.figshare.com/articles/dataset/Asymmetric_Dearomatization_of_1_Aminonaphthalene_Derivatives_by_Gold_Catalyzed_Intramolecular_Double_C_C_Bond_Formation/2208961
It
has been established that a cationic gold(I)/axially chiral
biaryl bisphosphine complex catalyzes asymmetric dearomatization of
1-aminonaphthalene derivatives by the intramolecular double C–C
bond formation. Two different dearomatization products were obtained
depending on the substituents on the benzyl groups at the alkyne termini.
2015-02-06 00:00:00
catalyze
intramolecular
Derivative
biaryl
Aminonaphthalene
cationic
benzyl groups
alkyne termini
derivative
aminonaphthalene
FormationIt
substituent
bisphosphine
formation
dearomatization products
Bond
chiral
Asymmetric Dearomatization
Intramolecular
bond