Asymmetric Dearomatization of 1‑Aminonaphthalene Derivatives by Gold-Catalyzed Intramolecular Double C–C Bond Formation Junko Oka Ryuichi Okamoto Keiichi Noguchi Ken Tanaka 10.1021/ol503698s.s001 https://acs.figshare.com/articles/dataset/Asymmetric_Dearomatization_of_1_Aminonaphthalene_Derivatives_by_Gold_Catalyzed_Intramolecular_Double_C_C_Bond_Formation/2208961 It has been established that a cationic gold­(I)/axially chiral biaryl bisphosphine complex catalyzes asymmetric dearomatization of 1-aminonaphthalene derivatives by the intramolecular double C–C bond formation. Two different dearomatization products were obtained depending on the substituents on the benzyl groups at the alkyne termini. 2015-02-06 00:00:00 catalyze intramolecular Derivative biaryl Aminonaphthalene cationic benzyl groups alkyne termini derivative aminonaphthalene FormationIt substituent bisphosphine formation dearomatization products Bond chiral Asymmetric Dearomatization Intramolecular bond