%0 Journal Article %A Oka, Junko %A Okamoto, Ryuichi %A Noguchi, Keiichi %A Tanaka, Ken %D 2015 %T Asymmetric Dearomatization of 1‑Aminonaphthalene Derivatives by Gold-Catalyzed Intramolecular Double C–C Bond Formation %U https://acs.figshare.com/articles/journal_contribution/Asymmetric_Dearomatization_of_1_Aminonaphthalene_Derivatives_by_Gold_Catalyzed_Intramolecular_Double_C_C_Bond_Formation/2208952 %R 10.1021/ol503698s.s004 %2 https://acs.figshare.com/ndownloader/files/3844483 %K catalyze %K intramolecular %K Derivative %K biaryl %K Aminonaphthalene %K cationic %K benzyl groups %K alkyne termini %K derivative %K aminonaphthalene %K FormationIt %K substituent %K bisphosphine %K formation %K dearomatization products %K Bond %K chiral %K Asymmetric Dearomatization %K Intramolecular %K bond %X It has been established that a cationic gold­(I)/axially chiral biaryl bisphosphine complex catalyzes asymmetric dearomatization of 1-aminonaphthalene derivatives by the intramolecular double C–C bond formation. Two different dearomatization products were obtained depending on the substituents on the benzyl groups at the alkyne termini. %I ACS Publications