10.1021/acs.organomet.5b00184.s002 Patrick W. Smith Patrick W. Smith T. Don Tilley T. Don Tilley Silane–Allyl Coupling Reactions of Cp*(<sup><i>i</i></sup>Pr<sub>2</sub>MeP)Fe(η<sup>3</sup>‑C<sub>3</sub>H<sub>5</sub>) and Synthetic Access to the Hydrido–Dinitrogen Complex Cp*(<sup><i>i</i></sup>Pr<sub>2</sub>MeP)FeH(N<sub>2</sub>) American Chemical Society 2015 Synthetic Access dehydrocoupling reactions iron allyl allyl group silane allyl ligand report reactions stoichiometric hydrosilation Cp 2015-06-08 00:00:00 Dataset https://acs.figshare.com/articles/dataset/Silane_Allyl_Coupling_Reactions_of_Cp_sup_i_i_i_sup_Pr_sub_2_sub_MeP_Fe_sup_3_sup_C_sub_3_sub_H_sub_5_sub_and_Synthetic_Access_to_the_Hydrido_Dinitrogen_Complex_Cp_sup_i_i_i_sup_Pr_sub_2_sub_MeP_FeH_N_sub_2_sub_/2205898 Herein we report reactions of the iron allyl complex Cp*­(<sup>i</sup>Pr<sub>2</sub>MeP)­Fe­(η<sup>3</sup>-C<sub>3</sub>H<sub>5</sub>) with sterically demanding silanes. These reactions lead to stoichiometric hydrosilation of the allyl ligand and dehydrocoupling reactions between the silane and the allyl group. Furthermore, this system has allowed access to a novel Si–H oxidative addition–reductive elimination equilibrium involving Cp*­(<sup>i</sup>Pr<sub>2</sub>MeP)­FeH<sub>2</sub>(SiH<sub>2</sub>DMP) and Cp*­(<sup>i</sup>Pr<sub>2</sub>MeP)­FeH­(N<sub>2</sub>), which was independently synthesized.