10.1021/acs.organomet.5b00184.s002
Patrick
W. Smith
Patrick
W.
Smith
T. Don Tilley
T. Don
Tilley
Silane–Allyl Coupling Reactions of Cp*(<sup><i>i</i></sup>Pr<sub>2</sub>MeP)Fe(η<sup>3</sup>‑C<sub>3</sub>H<sub>5</sub>) and Synthetic Access to the Hydrido–Dinitrogen
Complex Cp*(<sup><i>i</i></sup>Pr<sub>2</sub>MeP)FeH(N<sub>2</sub>)
American Chemical Society
2015
Synthetic Access
dehydrocoupling reactions
iron allyl
allyl group
silane
allyl ligand
report reactions
stoichiometric hydrosilation
Cp
2015-06-08 00:00:00
Dataset
https://acs.figshare.com/articles/dataset/Silane_Allyl_Coupling_Reactions_of_Cp_sup_i_i_i_sup_Pr_sub_2_sub_MeP_Fe_sup_3_sup_C_sub_3_sub_H_sub_5_sub_and_Synthetic_Access_to_the_Hydrido_Dinitrogen_Complex_Cp_sup_i_i_i_sup_Pr_sub_2_sub_MeP_FeH_N_sub_2_sub_/2205898
Herein
we report reactions of the iron allyl complex Cp*(<sup>i</sup>Pr<sub>2</sub>MeP)Fe(η<sup>3</sup>-C<sub>3</sub>H<sub>5</sub>) with
sterically demanding silanes. These reactions lead to stoichiometric
hydrosilation of the allyl ligand and dehydrocoupling reactions between
the silane and the allyl group. Furthermore, this system has allowed
access to a novel Si–H oxidative addition–reductive
elimination equilibrium involving Cp*(<sup>i</sup>Pr<sub>2</sub>MeP)FeH<sub>2</sub>(SiH<sub>2</sub>DMP) and Cp*(<sup>i</sup>Pr<sub>2</sub>MeP)FeH(N<sub>2</sub>), which was independently synthesized.