10.1021/acscatal.5b00861.s001 Théodore Vanbésien Théodore Vanbésien Eric Monflier Eric Monflier Frédéric Hapiot Frédéric Hapiot Supramolecular Emulsifiers in Biphasic Catalysis: The Substrate Drives Its Own Transformation American Chemical Society 2015 supramolecular Biphasic Catalysis organometallic catalyst Supramolecular Emulsifiers concentration range triglyceride alkyl chains Substrate Drives Own TransformationNaturally biphasic conditions 2015-07-02 00:00:00 Journal contribution https://acs.figshare.com/articles/journal_contribution/Supramolecular_Emulsifiers_in_Biphasic_Catalysis_The_Substrate_Drives_Its_Own_Transformation/2204056 Naturally occurring triglycerides have been hydroformylated through supramolecular means in the presence of cyclodextrins (CDs). During the course of the reaction, a transient supramolecular complex is formed between triglyceride alkyl chains and the appropriate CDs in a well-defined concentration range. The resulting CD/triglyceride supramolecular emulsifiers help convert the triglyceride CC double bonds in biphasic conditions using a water-soluble organometallic catalyst. The catalytic system could be efficiently recycled.