10.1021/acscatal.5b00861.s001
Théodore Vanbésien
Théodore
Vanbésien
Eric Monflier
Eric
Monflier
Frédéric Hapiot
Frédéric
Hapiot
Supramolecular Emulsifiers in Biphasic Catalysis:
The Substrate Drives Its Own Transformation
American Chemical Society
2015
supramolecular
Biphasic Catalysis
organometallic catalyst
Supramolecular Emulsifiers
concentration range
triglyceride alkyl chains
Substrate Drives
Own TransformationNaturally
biphasic conditions
2015-07-02 00:00:00
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Supramolecular_Emulsifiers_in_Biphasic_Catalysis_The_Substrate_Drives_Its_Own_Transformation/2204056
Naturally
occurring triglycerides have been hydroformylated through
supramolecular means in the presence of cyclodextrins (CDs). During
the course of the reaction, a transient supramolecular complex is
formed between triglyceride alkyl chains and the appropriate CDs in
a well-defined concentration range. The resulting CD/triglyceride
supramolecular emulsifiers help convert the triglyceride CC
double bonds in biphasic conditions using a water-soluble organometallic
catalyst. The catalytic system could be efficiently recycled.