%0 Generic
%A Navuluri, Chandrasekhar
%A Charette, André B.
%D 2015
%T Diastereoselective Fluorocyclopropanation of Chiral
Allylic Alcohols Using an α‑Fluoroiodomethylzinc
Carbenoid
%U https://acs.figshare.com/articles/dataset/Diastereoselective_Fluorocyclopropanation_of_Chiral_Allylic_Alcohols_Using_an_Fluoroiodo_methylzinc_Carbenoid/2200366
%R 10.1021/acs.orglett.5b02097.s002
%2 https://acs.figshare.com/ndownloader/files/3834916
%K diastereoselectivitie
%K carbinol
%K Chiral Allylic Alcohols
%K fluorocyclopropyl
%K building blocks
%K allylic
%K cyclopropanation reaction
%K aldehyde
%K transformation
%K CarbenoidChiral
%K enantioselective version
%K Diastereoselective Fluorocyclopropanation
%K formation
%K chiral
%K Fluoroiodo
%K Walsh
%X Chiral fluorocyclopropyl
carbinols were synthesized in high diastereoselectivities
via a zinc mediated cyclopropanation reaction, using sec-allylic alcohols as simple building blocks. An enantioselective
version of this transformation was achieved through in situ formation of chiral allylic zinc sec-alkoxides
from the requisite aldehydes using Walsh’s protocol.
%I ACS Publications