10.1021/sc500702q.s001
Shuguo Wang
Shuguo
Wang
Zehui Zhang
Zehui
Zhang
Bing Liu
Bing
Liu
Catalytic Conversion of Fructose and 5‑Hydroxymethylfurfural into 2,5-Furandicarboxylic Acid over a Recyclable Fe<sub>3</sub>O<sub>4</sub>–CoO<sub><i>x</i></sub> Magnetite Nanocatalyst
American Chemical Society
2015
FDCA
Catalytic conversion
base additive
reaction parameters
HMF
nonprecious metals
impregnation method
reaction temperature
15 h
reaction process
Catalytic Conversion
Fe 3O
2015-03-02 00:00:00
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Catalytic_Conversion_of_Fructose_and_5_Hydroxymethylfurfural_into_2_5_Furandicarboxylic_Acid_over_a_Recyclable_Fe_sub_3_sub_O_sub_4_sub_CoO_sub_i_x_i_sub_Magnetite_Nanocatalyst/2191936
A nano-Fe<sub>3</sub>O<sub>4</sub>–CoO<sub><i>x</i></sub> catalyst
was prepared via a simple wet impregnation method.
The nano-Fe<sub>3</sub>O<sub>4</sub>–CoO<sub><i>x</i></sub> catalyst showed good catalytic performance for the conversion
of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid (FDCA)
with <i>t</i>-BuOOH as the oxidant. Several important reaction
parameters were explored, with the highest FDCA yield of 68.6% obtained
from HMF after 15 h at a reaction temperature of 80 °C. One-pot
conversion of fructose into FDCA was also successful via two steps.
Catalytic conversion of fructose over Fe<sub>3</sub>O<sub>4</sub>@SiO<sub>2</sub>–SO<sub>3</sub>H yielded 93.1% HMF, which was oxidized
in situ into FDCA with a yield of 59.8%. Furthermore, recycling of
nano-Fe<sub>3</sub>O<sub>4</sub>–CoO<sub><i>x</i></sub> was accomplished with the help of a magnetic field. Nano-Fe<sub>3</sub>O<sub>4</sub>–CoO<sub><i>x</i></sub> showed
high stability in the reaction process. The use of nonprecious metals
and no requirement of a base additive made this method much more economical
and environmentally friendly.