10.1021/acs.joc.5b00331.s002 Dattatraya H. Dethe Dattatraya H. Dethe Balu D. Dherange Balu D. Dherange Enantioselective Total Syntheses of (+)-Hostmanin A, (−)-Linderol A, (+)-Methyllinderatin and Structural Reassignment of Adunctin E American Chemical Society 2015 Enantioselective linderol series Synthese enantioselective synthesis method product adunctin E Hostmanin Methyllinderatin hexahydrodibenzofuran derivatives spectroscopic data investigations Adunctin EA Friedel hostmanin methyllinderatin Linderol analysis reassignment Structural Reassignment 2015-05-01 00:00:00 Journal contribution https://acs.figshare.com/articles/journal_contribution/Enantioselective_Total_Syntheses_of_Hostmanin_A_Linderol_A_Methyllinderatin_and_Structural_Reassignment_of_Adunctin_E/2170648 A one-step protocol has been developed for the enantioselective synthesis of hexahydrodibenzofuran derivatives using a modified Friedel–Crafts reaction. The developed method was applied to the synthesis of a series of natural products including (+)-hostmanin A, (+)-methyllinderatin, and (−)-linderol A. The synthetic and spectroscopic data investigations led to the structural reassignment of natural product adunctin E, which was further confirmed by single-crystal X-ray analysis.