Sinha, Indranil Hepp, Alexander Schirmer, Birgitta Kösters, Jutta Neugebauer, Johannes Müller, Jens Regioselectivity of the C‑Metalation of 6‑Furylpurine: Importance of Directing Effects We report the C-metalation of 6-furylpurine with Pt<sup>2+</sup>, Pd<sup>2+</sup>, and Hg<sup>2+</sup>. The ligand binds the metal ions in a bidentate fashion, involving the N7 purine atom and one of the furyl carbon atoms. The regioselectivity is determined by the metal ion. Pt<sup>2+</sup> and Pd<sup>2+</sup> coordinate the furyl moiety in its β position and Hg<sup>2+</sup> in its electronically preferred α position. Regioselectivity;Pt;furyl carbon atoms;Pd;α position;regioselectivity;ligand;Importance;N 7 purine atom;furyl moiety;Hg;β position;metal ions;Furylpurine;bidentate fashion;Directing EffectsWe report;furylpurine;metal ion 2015-05-04
    https://acs.figshare.com/articles/dataset/Regioselectivity_of_the_C_Metalation_of_6_Furylpurine_Importance_of_Directing_Effects/2170192
10.1021/acs.inorgchem.5b00450.s003