Well-Defined Butadienyl Organocopper(I) Aggregates
from Zirconacyclopentadienes and CuCl: Synthesis and Structural Characterization
Liang Liu
Weizhi Geng
Qi Yang
Wen-Xiong Zhang
Zhenfeng Xi
10.1021/acs.organomet.5b00598.s002
https://acs.figshare.com/articles/dataset/Well_Defined_Butadienyl_Organocopper_I_Aggregates_from_Zirconacyclopentadienes_and_CuCl_Synthesis_and_Structural_Characterization/2132401
Two examples of mixed alkenyl/aryl
organocopper(I) aggregates possessing
conjugated alkenyl/aryl C–Cu bonds were synthesized by transmetalation
of zirconaindenes with CuCl. Single-crystal X-ray structural analysis
revealed tetrameric and hexameric structures. Butadienyl copper(I)
aggregates were also synthesized and structurally characterized for
further comparison. The preliminary reaction chemistry of the copper(I)
aggregates was studied.
2015-09-14 00:00:00
hexameric structures
Structural CharacterizationTwo examples
reaction chemistry
CuCl
aggregate
Butadienyl
alkenyl