%0 Generic %A Petrone, David A. %A Yen, Andy %A Zeidan, Nicolas %A Lautens, Mark %D 2015 %T Dearomative Indole Bisfunctionalization via a Diastereoselective Palladium-Catalyzed Arylcyanation %U https://acs.figshare.com/articles/dataset/Dearomative_Indole_Bisfunctionalization_via_a_Diastereoselective_Palladium_Catalyzed_Arylcyanation/2126452 %R 10.1021/acs.orglett.5b02403.s004 %2 https://acs.figshare.com/ndownloader/files/3760255 %K cyanation mechanism %K diastereoselectivity %K Pd %K bisfunctionalization %K diastereoselective arylcyanation %K indole %K Dearomative Indole Bisfunctionalization %K ArylcyanationThe %K method %K stereocenter %K dearomative %K formation %K benzylic %K Diastereoselective %K indoline scaffolds %X The first Pd-catalyzed dearomative indole bisfunctionalization via a diastereoselective arylcyanation is reported. This method facilitates the formation of diverse indoline scaffolds bearing congested stereocenters with high levels of diastereoselectivity. This also represents the first example of a cyanation mechanism involving a 2° benzylic Pd­(II) intermediate. %I ACS Publications