Structural–Spectrochemical Correlations of Variable Dimensionality Crystalline Metal–Organic Framework Materials in Hydrothermal Reactivity Patterns of Binary–Ternary Systems of Pb(II) with (a)Cyclic (Poly)carboxylate and Aromatic Chelator Ligands Catherine Gabriel Angelos A. Vangelis Catherine P. Raptopoulou Aris Terzis Vassilis Psycharis Maria Zervou Marko Bertmer Athanasios Salifoglou 10.1021/acs.cgd.5b00861.s002 https://acs.figshare.com/articles/dataset/Structural_Spectrochemical_Correlations_of_Variable_Dimensionality_Crystalline_Metal_Organic_Framework_Materials_in_Hydrothermal_Reactivity_Patterns_of_Binary_Ternary_Systems_of_Pb_II_with_a_Cyclic_Poly_carboxylate_and_Aromatic_Chelator_Ligands/2113600 Efforts to comprehend the structural–spectrochemical correlations of crystalline metal–organic framework materials of Pb­(II) with (a)­cyclic and aromatic chelators linked to photoluminescent applications led to the hydrothermal pH-specific synthesis of crystalline materials [Pb­{H<sub>2</sub>BTC}­(phen)­(H<sub>2</sub>O)]<sub><i>n</i></sub>·2<i>n</i>H<sub>2</sub>O­(<b>1</b>), [Pb<sub>2</sub>{CBTC}]<sub><i>n</i></sub>(<b>2</b>), [Pb<sub>4</sub>(phen)<sub>8</sub>{CBTC}<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>]<sub>3</sub>·70.3H<sub>2</sub>O­(<b>3</b>), and [Pb­{HCTA}­(H<sub>2</sub>O)<sub>2</sub>]<sub><i>n</i></sub>·<i>n</i>H<sub>2</sub>O­(<b>4</b>). X-ray studies showed that <b>1</b>–<b>4</b> exhibit unique architectures linked to 2D–3D coordination polymers formulated by Z-type units composed of Pb<sub>2</sub>O<sub>2</sub> cores, unusually high number of lattice–water molecules, and π–π and H-bond interactions. The contribution of the nature–structure properties of the aliphatic-(a)­cyclic organic (poly)­carboxylic/aromatic chelators-ligands to binary-ternary Pb­(II) reactivity weaves into the assembly of supramolecular networks, thereby providing clear structural–spectroscopic inter-relationships exemplifying the observed photoluminescent activity in a distinct MOF-linked fashion. 2015-11-04 00:00:00 photoluminescent activity photoluminescent applications supramolecular networks Hydrothermal Reactivity Patterns Aromatic Chelator LigandsEfforts Pb 2O cores