%0 Generic %A Henkelis, James J. %A Carruthers, Christopher J. %A Chambers, Scott E. %A Clowes, Rob %A Cooper, Andrew I. %A Fisher, Julie %A Hardie, Michaele J. %D 2015 %T Metallo-Cryptophanes Decorated with Bis-N-Heterocyclic Carbene Ligands: Self-Assembly and Guest Uptake into a Nonporous Crystalline Lattice %U https://acs.figshare.com/articles/dataset/Metallo_Cryptophanes_Decorated_with_Bis_N_Heterocyclic_Carbene_Ligands_Self_Assembly_and_Guest_Uptake_into_a_Nonporous_Crystalline_Lattice/2041929 %R 10.1021/ja508502u.s005 %2 https://acs.figshare.com/ndownloader/files/3613239 %K Pd 3L complexes act %K chelating ligands %K Pd 3L %K Pd 6L rearrangement %K Guest Uptake %X Pd3L2 metallo-cryptophane cages with cyclotriveratrylene-type L ligands can be stabilized by use of a bis-N-heterocyclic carbene as an auxiliary cis-protecting ligand, while use of more common protecting chelating ligands such as ethylenediamine saw a Pd3L2 to Pd6L8 rearrangement occur in solution. The crystalline Pd3L2 complexes act as sponges, taking up 1,2-dichorobenzene or iodine in a single-crystal-to-single-crystal fashion despite not exhibiting conventional porosity. %I ACS Publications