%0 Generic
%A Henkelis, James
J.
%A Carruthers, Christopher J.
%A Chambers, Scott E.
%A Clowes, Rob
%A Cooper, Andrew I.
%A Fisher, Julie
%A Hardie, Michaele J.
%D 2015
%T Metallo-Cryptophanes
Decorated with Bis-N-Heterocyclic
Carbene Ligands: Self-Assembly and Guest Uptake into a Nonporous Crystalline
Lattice
%U https://acs.figshare.com/articles/dataset/Metallo_Cryptophanes_Decorated_with_Bis_N_Heterocyclic_Carbene_Ligands_Self_Assembly_and_Guest_Uptake_into_a_Nonporous_Crystalline_Lattice/2041929
%R 10.1021/ja508502u.s005
%2 https://acs.figshare.com/ndownloader/files/3613239
%K Pd 3L complexes act
%K chelating ligands
%K Pd 3L
%K Pd 6L rearrangement
%K Guest Uptake
%X Pd3L2 metallo-cryptophane cages with cyclotriveratrylene-type
L ligands can be stabilized by use of a bis-N-heterocyclic carbene
as an auxiliary cis-protecting ligand, while use
of more common protecting chelating ligands such as ethylenediamine
saw a Pd3L2 to Pd6L8 rearrangement
occur in solution. The crystalline Pd3L2 complexes
act as sponges, taking up 1,2-dichorobenzene or iodine in a single-crystal-to-single-crystal
fashion despite not exhibiting conventional porosity.
%I ACS Publications