%0 Generic %A Johnson, Miles W. %A DiPasquale, Antonio G. %A Bergman, Robert G. %A Toste, F. Dean %D 2015 %T Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors %U https://acs.figshare.com/articles/dataset/Synthesis_of_Stable_Gold_III_Pincer_Complexes_with_Anionic_Heteroatom_Donors/2038440 %R 10.1021/om500663m.s005 %2 https://acs.figshare.com/ndownloader/files/3609753 %K Anionic Heteroatom DonorsA series %K bi %K compound %K heteroaom donors %K ligand scaffolds %K reduction potentials %K electrochemical studies %X A series of gold­(III) complexes supported by pyridine-based bis­(amidate), bis­(carboxylate), and bis­(iminothiolate) substituents is reported. These compounds represent rare examples of pincer-ligated gold­(III) centers with multiple anionic heteroaom donors. Reactivity and electrochemical studies demonstrate the stability of these compounds and the marked difference in reduction potentials with varying ligand scaffolds. %I ACS Publications