Nimmanwudipong, Tarit Runnebaum, Ron C. Brodwater, Kevin Heelan, Jennifer Block, David E. Gates, Bruce C. Design of a High-Pressure Flow-Reactor System for Catalytic Hydrodeoxygenation: Guaiacol Conversion Catalyzed by Platinum Supported on MgO A high-pressure once-through plug-flow-reactor system is reported for characterization of hydroprocessing reactions of biomass-derived compounds. All of the reactants are liquids. Data are presented for conversion of guaiacol catalyzed by Pt/MgO and, in much less detail, CoMo/Al<sub>2</sub>O<sub>3</sub>. The data demonstrate the advantages of high pressure in such reactions, determining a pseudo-first-order rate constant for guaiacol conversion at 523 K and 69 bar of approximately 55 L of organic reactant solution (g of catalyst)<sup>–1</sup> h<sup>–1</sup>. This value is 2 orders of magnitude greater than that observed at 573 K and 1.4 bar. Guaiacol Conversion Catalyzed;Pt;characterization;573 K;2 orders;MgOA;data;guaiacol conversion;Catalytic Hydrodeoxygenation;reactant solution;reactants;1.4 bar;hydroprocessing reactions;magnitude;catalyst;CoMo;compound;69 bar;55 L;523 K 2015-12-17
    https://acs.figshare.com/articles/journal_contribution/Design_of_a_High_Pressure_Flow_Reactor_System_for_Catalytic_Hydrodeoxygenation_Guaiacol_Conversion_Catalyzed_by_Platinum_Supported_on_MgO/2029047
10.1021/ef4020026.s001