10.1021/ef4020026.s001
Tarit Nimmanwudipong
Tarit
Nimmanwudipong
Ron C. Runnebaum
Ron C.
Runnebaum
Kevin Brodwater
Kevin
Brodwater
Jennifer Heelan
Jennifer
Heelan
David
E. Block
David
E.
Block
Bruce C. Gates
Bruce C.
Gates
Design of a High-Pressure Flow-Reactor System for
Catalytic Hydrodeoxygenation: Guaiacol Conversion Catalyzed by Platinum
Supported on MgO
American Chemical Society
2015
Guaiacol Conversion Catalyzed
Pt
characterization
573 K
2 orders
MgOA
data
guaiacol conversion
Catalytic Hydrodeoxygenation
reactant solution
reactants
1.4 bar
hydroprocessing reactions
magnitude
catalyst
CoMo
compound
69 bar
55 L
523 K
2015-12-17 00:41:51
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Design_of_a_High_Pressure_Flow_Reactor_System_for_Catalytic_Hydrodeoxygenation_Guaiacol_Conversion_Catalyzed_by_Platinum_Supported_on_MgO/2029047
A high-pressure once-through plug-flow-reactor
system is reported
for characterization of hydroprocessing reactions of biomass-derived
compounds. All of the reactants are liquids. Data are presented for
conversion of guaiacol catalyzed by Pt/MgO and, in much less detail,
CoMo/Al<sub>2</sub>O<sub>3</sub>. The data demonstrate the advantages
of high pressure in such reactions, determining a pseudo-first-order
rate constant for guaiacol conversion at 523 K and 69 bar of approximately
55 L of organic reactant solution (g of catalyst)<sup>–1</sup> h<sup>–1</sup>. This value is 2 orders of magnitude greater
than that observed at 573 K and 1.4 bar.