10.1021/acs.jpclett.9b03556.s005
Lu-Lu Chu
Lu-Lu
Chu
Tie Zhang
Tie
Zhang
Wan-Ying Zhang
Wan-Ying
Zhang
Ping-Ping Shi
Ping-Ping
Shi
Ji-Xing Gao
Ji-Xing
Gao
Qiong Ye
Qiong
Ye
Da-Wei Fu
Da-Wei
Fu
Three-Dimensional Metal-Free Molecular Perovskite
with a Thermally Induced Switchable Dielectric Response
American Chemical Society
2020
dielectric response behaviors
report temperature-dielectric-responsive metal-free perovskite
BF
Three-Dimensional Metal-Free Molecular Perovskite
application
representative switchable dielectric materials
H 2 dabco
switchable dielectric perovskite materials show
formula ABX 3
dielectric response
Thermally Induced Switchable Dielectric Response Temperature-responsive materials
2020-02-14 15:08:43
Dataset
https://acs.figshare.com/articles/dataset/Three-Dimensional_Metal-Free_Molecular_Perovskite_with_a_Thermally_Induced_Switchable_Dielectric_Response/11855613
Temperature-responsive
materials with switching physical properties
have been widely researched. Among them, the switchable dielectric
perovskite materials show potential applications in the electrical
and electronic industries and even the intelligence industries. However,
perovskite oxides and hybrid organic–inorganic perovskites,
as the most representative switchable dielectric materials, are limited
by bad biocompatibility. Herein, we report temperature-dielectric-responsive
metal-free perovskite (H<sub>2</sub>dabco)(NH<sub>4</sub>)[BF<sub>4</sub>]<sub>3</sub> constructed by the strategy of substituting
the B site in the general formula ABX<sub>3</sub> (doubly protonated
1,4-diazabicyclo[2.2.2]octane = H<sub>2</sub>dabco). Meanwhile, structurally
similar hybrid material (H<sub>2</sub>dabco)Rb[BF<sub>4</sub>]<sub>3</sub> was designed as a control. They exhibit similar phase-transition
characteristics and dielectric response behaviors around 333 K. More
interestingly, the ordered–disordered transformation of their
organic “spherical” cations (H<sub>2</sub>dabco) was
deemed to produce their phase transitions and dielectric response
switching. Given its ability to generate a dielectric response, (H<sub>2</sub>dabco)(NH<sub>4</sub>)[BF<sub>4</sub>]<sub>3</sub> will show
the potential application of metal-free perovskite in a future thermal
sensing device.