Nanoarchitecture through Strained Molecules: Cubane-Derived Scaffolds and the Smallest Carbon Nanothreads Haw-Tyng Huang Li Zhu Matthew D. Ward Tao Wang Bo Chen Brian L. Chaloux Qianqian Wang Arani Biswas Jennifer L. Gray Brooke Kuei George D. Cody Albert Epshteyn Vincent H. Crespi John V. Badding Timothy A. Strobel 10.1021/jacs.9b12352.s002 https://acs.figshare.com/articles/dataset/Nanoarchitecture_through_Strained_Molecules_Cubane-Derived_Scaffolds_and_the_Smallest_Carbon_Nanothreads/11832942 Relative to the rich library of small-molecule organics, few examples of ordered extended (i.e., nonmolecular) hydrocarbon networks are known. In particular, sp<sup>3</sup> bonded, diamond-like materials represent appealing targets because of their desirable mechanical, thermal, and optical properties. While many covalent organic frameworks (COFs)extended, covalently bonded, and porous structureshave been realized through molecular architecture with exceptional control, the design and synthesis of dense, covalent extended solids has been a longstanding challenge. Here we report the preparation of a sp<sup>3</sup>-bonded, low-dimensional hydrocarbon synthesized via high-pressure, solid-state diradical polymerization of cubane (C<sub>8</sub>H<sub>8</sub>), which is a saturated, but immensely strained, cage-like molecule. Experimental measurements show that the obtained product is crystalline with three-dimensional order that appears to largely preserve the basic structural topology of the cubane molecular precursor and exhibits high hardness (comparable to fused quartz) and thermal stability up to 300 °C. Among the plausible theoretical candidate structures, one-dimensional carbon scaffolds comprising six- and four-membered rings that pack within a pseudosquare lattice provide the best agreement with experimental data. These diamond-like molecular rods with extraordinarily small thickness are among the smallest members in the carbon nanothread family, and calculations indicate one of the stiffest one-dimensional systems known. These results present opportunities for the synthesis of purely sp<sup>3</sup>-bonded extended solids formed through the strain release of saturated molecules, as opposed to only unsaturated precursors. 2020-02-10 19:04:09 covalent carbon nanothread family sp 3 solid diamond-like hydrocarbon precursor cubane COF Smallest Carbon Nanothreads synthesis Experimental measurements show molecule