Facile Incorporation of Au Nanoparticles into an Unusual Twofold Entangled Zn(II)-MOF with Nanocages for Highly Efficient CO<sub>2</sub> Fixation under Mild Conditions Yun-Long Wu Guo-Ping Yang Shan Cheng Jinjie Qian Daidi Fan Yao-Yu Wang 10.1021/acsami.9b17348.s002 https://acs.figshare.com/articles/dataset/Facile_Incorporation_of_Au_Nanoparticles_into_an_Unusual_Twofold_Entangled_Zn_II_-MOF_with_Nanocages_for_Highly_Efficient_CO_sub_2_sub_Fixation_under_Mild_Conditions/11310482 Herein, a new porous Zn­(II)-based metal–organic framework (MOF <b>1</b>) has been prepared, the structure of which featured a twofold entangled motif based on two typical secondary building units (SBUs). The gas sorption studies indicated that MOF <b>1</b> may be explored as a useful platform to encapsulate metallic nanoparticles. Then the Au@<b>1</b> composite has been prepared via a facile incorporation method without extra reducing agents. The Au@<b>1</b> composite has been fully characterized by HRTEM, SEM-EDX, PXRD, gas sorption, XPS, ICP, etc. Catalytic experiments showed that the Au@<b>1</b> composite had a perfect catalytic performance in CO<sub>2</sub> fixation for epoxides with different substituents under mild conditions. 2019-12-03 15:21:09 Unusual Twofold Catalytic agent CO 2 fixation nanoparticle gas sorption studies epoxide platform Efficient CO 2 Fixation Incorporation Entangled performance MOF 1 Mild Conditions Herein experiment Facile Nanocage substituent framework incorporation XPS HRTEM ICP SEM-EDX Zn SBU motif method Nanoparticle PXRD