%0 Journal Article %A Wang, Xiaofeng %A Ou, Yingcong %A Peng, Zhenbo %A Yu, Guodian %A Huang, Yuanting %A Li, Xianwei %A Huo, Yanping %A Chen, Qian %D 2019 %T TBHP/NH4I‑Mediated Direct N–H Phosphorylation of Imines and Imidates %U https://acs.figshare.com/articles/journal_contribution/TBHP_NH_sub_4_sub_I_Mediated_Direct_N_H_Phosphorylation_of_Imines_and_Imidates/10048487 %R 10.1021/acs.joc.9b02301.s001 %2 https://acs.figshare.com/ndownloader/files/18108935 %K TBHP %K Imidate %K I-mediated %K group compatibility %K phosphoryl %K imine %K Imine %K transformation %K Phosphorylation %K metal-free %K construction %K formation %K cross-dehydrogenative %K compound %K CDC %K phosphorylation %K bond %X A direct and practical metal-free N–H phosphorylation has been achieved via the TBHP/NH4I-mediated cross-dehydrogenative coupling (CDC) reactions between imines/imidates and P­(O)H compounds. This transformation provides an efficient synthetic route to the construction of P–N bonds with good functional group compatibility, leading to the formation of N-phosphoryl­imines and N-phosphoryl­imidates in up to 95% yield (33 examples) under mild conditions. %I ACS Publications